CITGO PETROLEUM CORP -- CITGARD 500 MOTOR OIL, SAE 40, 22-404  -- 9150-00N019699
<pre>=====================  Product Identification  =====================

Product ID:CITGARD 500 MOTOR OIL, SAE 40, 22-404
MSDS Date:06/29/1993
FSC:9150
NIIN:00N019699
MSDS Number: CCRBN
=== Responsible Party ===
Company Name:CITGO PETROLEUM CORP
Box:3758
City:TULSA
State:OK
ZIP:74102
Country:US
Info Phone Num:918-495-5933
Emergency Phone Num:918-495-4700;800-424-9300(CHEMTREC)
CAGE:7X110
=== Contractor Identification ===
Company Name:CITGO PETROLEUM CORP
Address:6100 S YALE AVE
Box:3758
City:TULSA
State:OK
ZIP:74102
Country:US
Phone:918-495-5933
CAGE:7X110

=============  Composition/Information on Ingredients  =============

Ingred Name:ING 11: CNTNRS MAY CONTAIN PRODUCT RESIDUE WHICH COULD INCL
    FLAMMABLE OR EXPLOSIVE VAPORS. CONSULT APPROPRIATE (ING 13)
RTECS #:9999999ZZ

Ingred Name:ING 12: FEDERAL, STATE AND LOCAL AUTHORITIES BEFORE
    REUSING, RECONDITIONING, RECLAIMING, RECYCLING OR DISPOSING (ING
    14)
RTECS #:9999999ZZ

Ingred Name:ING 13: OF EMPTY CONTAINERS &/OR WASTE RESIDUES OF THIS
    PRODUCT.
RTECS #:9999999ZZ

Ingred Name:VENT: MANDATED STANDARDS. RESPONSIBLE INDIVIDUALS SHOULD
    EVALUATE AIR CONCENTRATIONS OF SPECIFIC REGULATED CHEMICALS.
RTECS #:9999999ZZ

Ingred Name:REFINED PETROLEUM OILS CONTAINING INGREDIENTS 2-5.	LD50:
    (ORAL, RAT) >5 G/KG
RTECS #:9999999ZZ
Fraction by Wt: >80%
OSHA PEL:N/K 
ACGIH TLV:N/K 

Ingred Name:MINERAL OIL, PETROLEUM DISTILLATES, SOLVENT-DEWAXED HEAVY
    PARAFFINIC (SEVERE SOLVENT-REFINING &/OR HYDROTREATMENT)
CAS:64742-65-0
RTECS #:PY8038501
OSHA PEL:N/K 
ACGIH TLV:N/K 

Ingred Name:MINERAL OIL, PETROLEUM DISTILLATES, SOLVENT-REFINED
    (SEVERE) HEAVY PARAFFINIC
CAS:64741-88-4
RTECS #:PY8040501
OSHA PEL:N/K 
ACGIH TLV:N/K 

Ingred Name:SOLVENT REFINED RESIDUM
CAS:64742-01-4
OSHA PEL:N/K 
ACGIH TLV:N/K 

Ingred Name:SOLVENT DEWAXED RESIDUAL OIL (PETROLEUM)
CAS:64742-62-7
OSHA PEL:N/K 
ACGIH TLV:N/K 

Ingred Name:DETERGENT INHIBITOR (CONTAINS INGREDIENT 7)
Fraction by Wt: <20%
OSHA PEL:N/K 
ACGIH TLV:N/K 

Ingred Name:PHOSPHORODITHOIC ACID, O-O-D1 C1-14-ALKYL ESTERS, ZINC
    SALTS (2:1) (ZDDP); (ZINC DIALKYLDITHIOPHOSPHATE)
CAS:68649-42-3
Fraction by Wt: <4%
OSHA PEL:N/K 
ACGIH TLV:N/K 

Ingred Name:SUPDAT: LAVAGE MAY BE CONSIDERED. SUBCUTANEOUS INJECTION
    REQS PROMPT SURGICAL DEBRIDEMENT. IF NOT FAMILIAR (ING 9)
RTECS #:9999999ZZ

Ingred Name:ING 8: W/TECHNIQUE, SEEK SKILLED ADVICE.
RTECS #:9999999ZZ

Ingred Name:SPILL PROC: AROUND SPILL AREA. REPORT SPILLS AS REQUIRED TO
    APPROPRIATE AUTHORITIES.
RTECS #:9999999ZZ

Ingred Name:HNDLG/STOR PRECS: SKIN CANCER IN LAB ANIMALS. AFTER
    DRAINING OIL, WASH SKIN THOROUGHLY W/SOAP & WATER. EMPTY (ING 12)
RTECS #:9999999ZZ

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:SEE INGREDIENT 1
Routes of Entry: Inhalation:YES  Skin:YES  Ingestion:YES
Reports of Carcinogenicity:NTP:NO    IARC:NO	OSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHAL: LOW RISK AT AMBIENT
    TEMPS. MISTS/FUMES MAY CAUSE DIZZINESS, HEADACHE, NAUSEA,
    RESPIRATORY IRRIT OR CHEM PNEUM. MISTS ABOVE TLV MAY CAUSE CHEM
    PNEUM. SKIN: MILD IRRITANT. EYES: MAY BE MIL DLY IRRITATING.
    INGEST: LOW TOXICITY. IF LESS THAN ONE OUNCE IS INGESTED, MATERIAL
    MAY PASS THRU SYSTEM(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: W/OUT HARM. ON INGEST OF LARGE QTYS
    SLIGHT GI DISCOMFORT, DIARRHEA & HEADACHE MAY OCCUR. APPROX ORAL
    LETHAL DOSE IS 1 PINT TO 1 QUART FOR 159 LB HUMAN ADULT. INJECTION:
    SUBCUTANEOUS OR INTRA MUSCULAR INJECTION MAY CAUSE IRRIT, ERYTHEMA,
    EDEMA. CHRONIC: DERMAL, PRLNGD & RPTD EXPOS MAY CAUSE DRYING OF
    (SUPDAT)
Medical Cond Aggravated by Exposure:NONE.

=======================  First Aid Measures  =======================

First Aid:INHAL: REMOVE FROM EXPOSURE TO INCIDENTAL FUMES & PROVIDE
    RESP SUPPORT IF NECESSARY. SEEK MED AID. SKIN: WASH W/SOAP & WATER.
    DO NOT WEAR HEAVILY CONTAMD CLTHG BEFORE LAUNDERING. EYES: FLUSH
    W/LARGE V OLUMES OF WATER FOR AT LEAST 15 MIN. SEEK MD IF ANY
    COMPLICATIONS ARISE. INGEST: INDUCE VOMIT & SEEK MED AID.
    INJECTION: SEEK MED AID IMMED. SUBCUTANEOUS INJECTIONS IS MED
    EMERGENCY. NOTES TO (SUPDAT)

=====================  Fire Fighting Measures  =====================

Flash Point Method:PMCC
Flash Point:414F,212C
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM, WATER FOG.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
    EQUIPMENT .
Unusual Fire/Explosion Hazard:WATER MAY CAUSE FROTHING.

==================  Accidental Release Measures  ==================

Spill Release Procedures:REMOVE SOURCES OF HEAT OR IGNIT. PROVIDE ADEQ
    VENT. SM SPILLS: TAKE UP W/NONCOMBUST ABSORB SUCH AS FULLERS EARTH
    OR SAND. PLACE INTO CNTNRS FOR LATER DISP. LG SPILLS: CONTAIN SPILL
    IN EARTHEN DIKES FO R LATER RECOVERY. CONTROL IGNIT SOURCES(ING 10)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

======================	Handling and Storage  ======================

Handling and Storage Precautions:KEEP CNTNR TIGHTLY CLOSED & AWAY FROM
    HEAT & FLAME. AVOID PRLNGD SKIN CONTACT W/USED MOTOR OILS.
    CONTINUOUS CONTACT W/USED OIL HAS CAUSED (ING 11)
Other Precautions:PROT MEASURES DURING REPAIR & MAINTENANCE OF CONTAMD
    EQUIP: REFER TO SPEC PROT INFO. WASH EXPOS SKIN THOROUGHLY W/SOAP &
    WATER. REMOVE SOILED CLTHG. USE POLYMER GLOVES IF EXTENDED, DIRECT
    CONTACT IS E XPECTED. AVOID PRLNGD CNTCT W/USED OIL.

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:IF HIGH VAPOR CONCENTRATION IS EXPECTED, USE
    NIOSH APPROVED RESPIRATOR FOR ORGANIC VAPORS.
Ventilation:USE IN WELL VENTD AREA. IN CONFINED SPACES, MECH VENT MAY
    BE REQD TO KEEP LEVELS OF CERTAIN COMPONENTS BELOW (ING 15)
Protective Gloves:OIL IMPERVIOUS GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
    WEAR BODY-COVERING WORK CLOTHES TO AVOID PROLONGED OR REPEATED
    EXPOSURE.
Work Hygienic Practices:LAUNDER SOILED WORK CLOTHES BEFORE REUSE.
Supplemental Safety and Health
FL PT/METH: 468F,242C/COC. EFTS OF OVEREXP: SKIN. AVOID PRLNGD SKIN
    CNTCT W/USED MOTOR OIL. CONTINUOUS CONTACT HAS CAUSED SKIN CANCER
    IN LAB ANIMALS. FIRST AID PROC: MD:FOLLOWING INGEST, AT A SAYBOLT 
    VISCOSITY OF APPROX 775 AT 100F, RISK OF ASPIR INTO LUNGS IS
    NON-SIGNIFICANT. FOR QTYS ABOVE 1 OZ, EMESIS OR (ING 8)

==================  Physical/Chemical Properties  ==================

Boiling Pt:B.P. Text:720F,382C
Vapor Pres:<1X10(-3)
Vapor Density:>1
Spec Gravity:0.89 (H*2O=1)
Evaporation Rate &amp; Reference:<1 (BUTYL ACETATE=1)
Solubility in Water:NEGLIGIBLE (BY WT)
Appearance and Odor:AMBER LIQUID; MILD ODOR.
Percent Volatiles by Volume:NEGLIG

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
STRONG OXIDANTS, STRONG ACIDS, CAUSTICS.
Stability Condition to Avoid:NONE.
Hazardous Decomposition Products:CARBON DIOXIDE (CARBON MONOXIDE UNDER
    INCOMPLETE COMBUSTION), TRACES OF OXIDES OF SULFUR, ZINC,
    PHOSPHORUS & CALCIUM.

====================  Disposal Considerations  ====================

Waste Disposal Methods:IT IS RESPONSIBILITY OF USER TO DETERM IF MATL
    IS HAZ WASTE AT TIME OF DISP. CHECK BEFORE DISP TO BE SURE YOU ARE
    IN COMPLIANCE W/ALL APPLIC FED, STATE & LOC LAWS & REGS. TREAT USED
    OIL ACCDG TO CURRE NT RULES & REGS. RCRA EMER HOTLINE
    #:800-424-9346.

 Disclaimer (provided with this information by the compiling agencies):
 This information is formulated for use by elements of the Department
 of Defense.  The United States of America in no manner whatsoever,
 expressly or implied, warrants this information to be accurate and
 disclaims all liability for its use.  Any person utilizing this
 document should seek competent professional advice to verify and
 assume responsibility for the suitability of this information to their
 particular situation.