SUPELCO INC -- 48411 FREON 113/1X1ML/MEOH/1000UG/ML  -- 6810-00F037600
<pre>=====================  Product Identification  =====================

Product ID:48411 FREON 113/1X1ML/MEOH/1000UG/ML
MSDS Date:02/03/1994
FSC:6810
NIIN:00F037600
MSDS Number: BWJLT
=== Responsible Party ===
Company Name:SUPELCO INC
Address:SUPELCO PARK
City:BELLEFONTE
State:PA
ZIP:16823-0048
Country:US
Info Phone Num:814-359-3441
Emergency Phone Num:814-359-3441
CAGE:54968
=== Contractor Identification ===
Company Name:SIGMA-ALDRICH INC.
Address:3050 SPRUCE STREET
Box:14508
City:ST. LOUIS
State:MO
ZIP:63103
Country:US
Phone:314-771-5765/414-273-3850X5996
CAGE:54968

=============  Composition/Information on Ingredients  =============

Ingred Name:FREON 113, 1,1,2,-TRICHLORO-1,2,2,-TRIFLUOROETHANE,
    TRICHLOROTRIFLUROETHANE
CAS:76-13-1
RTECS #:KJ4000000
Fraction by Wt: 0.1%
Other REC Limits:1000 PPM
OSHA PEL:1000 PPM
ACGIH TLV:1000 PPM
Ozone Depleting Chemical:1

Ingred Name:METHANOL (METHYL ALCOHOL), COLUMBIAN SPIRITS
CAS:67-56-1
RTECS #:PC1400000
Fraction by Wt: 99-100%
Other REC Limits:200 PPM
OSHA PEL:260 MG/CUM
ACGIH TLV:262 MG/CUM (SKIN)
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:ORAL LD50(RAT): 5628 MG/KG  METHANOL
Routes of Entry: Inhalation:YES  Skin:NO  Ingestion:YES
Reports of Carcinogenicity:NTP:NO    IARC:NO	OSHA:NO
Health Hazards Acute and Chronic:INHALATION: HARMFUL. INGESTION: FATAL.
    GASTROINTESTINAL DISTURBANCES. EYES: MAY CAUSE BLINDNESS.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:HEADACHE, NAUSEA, GI DISTURBANCES

=======================  First Aid Measures  =======================

First Aid:EYES: FLUSH W/WATER FOR 15 MINS. SKIN: FLUSH W/PLENTY OF
    WATER. INHALATION: MOVE TO FRESH AIR. GIVE OXYGEN/CPR IF NECESSARY.
    INGESTION: NEVER GIVE ANYTHING BY MOUTH IF UNCONSCIOUS. NEVER TRY
    TO MAKE A N UNCONSCIOUS PERSON VOMIT. IF CONSCIOUS GIVE 2
    TABLESPOONS OF BAKING SODA IN A GLASS OF WATER & PRESS FINGERS TO
    BACK OF TONGUE TO INDUCE VOMITING. OBTAIN MEDICAL ATTENTION IN ALL
    CASES.

=====================  Fire Fighting Measures  =====================

Flash Point:50F
Lower Limits:6
Upper Limits:36.5
Extinguishing Media:CO2, DRY CHEMICAL, ALCOHOL FOAM
Fire Fighting Procedures:WEAR SELF CONTAINED BREATHING APPARATUS WHEN
    FIGHTING A CHEMICAL FIRE.

==================  Accidental Release Measures  ==================

Spill Release Procedures:TAKE UP W/ABSORBENT MATERIAL. VENTILATE AREA.
    ELIMINATE ALL IGNITION SOURCES.

======================	Handling and Storage  ======================

Handling and Storage Precautions:STORE IN SEALED CONTAINER IN A
    FREEZER. KEEP AWAY FROM OXDIZERS & IGNITION SOURCES.
Other Precautions:AVOID EYE/SKIN CONTACT. AVOID BREATHING VAPORS.

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:WEAR FACE MASK W/ORGANIC VAPOR CANISTER.
Ventilation:USE ONLY IN WELL VENTILATED AREA.
Protective Gloves:RUBBER
Eye Protection:PROTECTIVE GLASSES
Supplemental Safety and Health

==================  Physical/Chemical Properties  ==================

Boiling Pt:B.P. Text:149F
Melt/Freeze Pt:M.P/F.P Text:-144.4F
Vapor Pres:100
Vapor Density:1.1
Spec Gravity:0.79
Evaporation Rate &amp; Reference:(ETHER=1): >1
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR COLORLESS LIQUID.
Percent Volatiles by Volume:100

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS, CHROMIC ANHYDRIDE, LEAD PERCHLORATE, PERCHLORIC
    ACIDS.
Stability Condition to Avoid:IGNITION SOURCES.
Hazardous Decomposition Products:HYDROGEN CHLORIDE, HYDROGEN FLUORIDE.

====================  Disposal Considerations  ====================

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE &
    FEDERAL REGULATINS.

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 This information is formulated for use by elements of the Department
 of Defense.  The United States of America in no manner whatsoever,
 expressly or implied, warrants this information to be accurate and
 disclaims all liability for its use.  Any person utilizing this
 document should seek competent professional advice to verify and
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 particular situation.