ALLIED CORP., ALLIED CHEMICAL,CSS DEPT. -- GENESOLV D SOLVENT,FLUOROCARBON(FREON) 113  -- 6750-01-003-7668
<pre>=====================  Product Identification  =====================

Product ID:GENESOLV D SOLVENT,FLUOROCARBON(FREON) 113
MSDS Date:05/27/1987
FSC:6750
NIIN:01-003-7668
MSDS Number: BJZQC
=== Responsible Party ===
Company Name:ALLIED CORP., ALLIED CHEMICAL,CSS DEPT.
Address:COLUMBIA RD & PARK AVE
Box:1087R
City:MORRISTOWN
State:NJ
ZIP:07960
Country:US
Info Phone Num:201-455-4157
Emergency Phone Num:201-455-2000
Preparer's Name:GENE TAYLOR (HAYWARD CO)
CAGE:JO859
=== Contractor Identification ===
Company Name:ALLIED CORP., ALLIED CHEMICAL,CSS DEPT.
Address:COLUMBIA RD & PARK AVE
Box:1087R
City:MORRISTOWN
State:NJ
ZIP:07960
Country:US
Phone:201-455-2000
CAGE:JO859
Company Name:ALLIED-SIGNAL INC
Address:Box:2332R
City:MORRISTOWN
State:NJ
ZIP:07962-2332
Country:US
Phone:201-455-4414
CAGE:1L164
Company Name:RESEARCH TECHNOLOGY INTERNATIONAL
Address:4700 CHASE AVE
Box:City:LINCOLNWOOD
State:IL
ZIP:60646-1608
Country:US
CAGE:50448
Company Name:THOMPSON-HAYWARD CHEMICAL CO
Address:5200 SPEAKER RD
Box:City:KANSAS CITY
State:KS
ZIP:66106
Country:US
Phone:913-321-3131
CAGE:5G633

=============  Composition/Information on Ingredients  =============

Ingred Name:1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE (FREON 113)  (SARA
    III)
CAS:76-13-1
RTECS #:KJ4000000
Fraction by Wt: 100%
Other REC Limits:NONE SPECIFIED
OSHA PEL:1000PPM/1250STEL
ACGIH TLV:1000PPM/1250STEL9192
Ozone Depleting Chemical:1

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:LD 50 ORAL RAT 45MG/KG
Routes of Entry: Inhalation:YES  Skin:YES  Ingestion:YES
Reports of Carcinogenicity:NTP:NO    IARC:NO	OSHA:NO
Health Hazards Acute and Chronic:INHALATION: VAPORS HEAVIER THAN AIR
    AND CAN CAUSE SUFFOCATION BY REDUCING OXYGEN AVAILABLE FOR
    BREATHING. BREATHING HIGH CONCENTRATIONS OF VAPOR CAUSE HEAVYNESS
    IN THE HEAD,DROWSINESS, GIDDINESS,SHORT NESS OF BREATH,AND MAY LEAD
    TO NARCOSIS,CARDIAC IRREGULARITIES,UNCONSCIOUSNESS OR DEATH.
    SKIN:MAY DEFAT.EYES:IRRITATION.
Explanation of Carcinogenicity:FREON 113 IS NOT LISTED AS A CARCINOGEN
    BY IARC, NTP OR OSHA.
Effects of Overexposure:INHALATION: BREATHING HIGH CONCENTRATIONS OF
    VAPOR MAY CAUSE HEADEDNESS,GIDDINESS, SHORTNESS OF BREATH, AND MAY
    LEAD TO NARCOSIS, CARDIAC IRREGULARITIES, UNCONSCIOUSNESS OR DEATH.
    SKIN:IRRITANT. EXCES SIVE CONTACT MAY DEFAT SKIN. EYES:VAPOR- MILD
    IRRITANT; LIQ - IRRITANT; INGESTION: LOW TOXICITY.
Medical Cond Aggravated by Exposure:SKIN DISEASE - FREON 113 IS A
    DEFATTING AGENT AND CAN CAUSE DERMATITIS ON PROLONGED EXPOSURE.
    PERSONS WITH PRE- EXISTING SKIN DISORDERS MAY BE MORE SUSCEPTIBLE
    TO THE EFFECTS OF THIS AGENT.

=======================  First Aid Measures  =======================

First Aid:INHALATION: REMOVE TO FRESH AIR, CALL A PHYSICIAN. IF NOT
    BREATHING, GIVE ARTIFICIAL RESPIRATION.IF BREATHING IS DIFFICULT,
    GIVE OXYGEN. DO NOT GIVE EPINEPHRINE OR SIMILAR DRUGS. EYE: FLUSH
    WITH WATER . SKIN: FLUSH WITH WATER. IF IRRITATIONPERSISTS, GET
    MEDICAL ATTENTION. ORAL: GET MEDICAL ATTENTION IMMEDIATELY. INDUCE
    VOMITING BY GIVING TWO GLASSES OF WATER. CALL A PHYSICIAN.

=====================  Fire Fighting Measures  =====================

Flash Point:NONE
Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY
    CHEMICAL.
Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A
    FULL FACED SELF CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED
    CONTAINERS WITH WATER SPRAY. CONTAIN RUNOFF.
Unusual Fire/Explosion Hazard:PROLONGED EXPOSURE TO WHITE METALS WILL
    CAUSE CORROSION.EXOTHERMIC REACTION OCCURE WITH MOLTEN
    ALUMINUM,BARIUM,AND LITHIUM SHAVINGS.

==================  Accidental Release Measures  ==================

Spill Release Procedures:VENTILATE AREA. EVACUATE UNPROTECTED PERSONS.
    ELIMINATE IGNITION SOURCES SND SHUT OFF LEAK. ABSORB LIQUID WITH
    COMMERCIAL ABSORBENT,SHOVEL INTO METAL DRUMS.LARGE SPILL: DIKE UP
    WITHABSORBENT AND PUMP  INTO DRUMS,MAKING SURE PUMP DOES NOT GET
    OVERHEATD
Neutralizing Agent:NONE

======================	Handling and Storage  ======================

Handling and Storage Precautions:STORE IN A CLEAN, COOL, DRY AND WELL-
    VENTILATED AREA. PROTECT CONTAINERS FROM PHYSICAL DAMAGE AND KEEP
    CLOSED. OPEN BUNG SLOWLY AND CAUTIOSLY.
Other Precautions:AVOID BREATHING VAPOR, LIQUID CONTACT WITH EYES, SKIN
    OR CLOTHING. TANK-CLEANING PERSONNEL SHOULD USE ONLY FORMAL TANK
    ENTRY PROCEDURE BASED ON RECOGNIZED SAFETY PRINCIPLES. EMPTY
    CONTAINERS MAY CONTA IN PRODUCT RESIDUES/VAPORS.

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:NONE REQUIRED FOR ADEQUATELY VENTED WORK
    SITUATIONS. FOR ACCIDENTAL OR NON-VENTILATED SITUATIONS, USE A
    SELF- CONTAINED BREATHING APPARATUS OR SUPPLIED-AIR RESPIRATOR,
    APPROVED BY NIOSH.
Ventilation:PROVIDE LOCAL EXHAUST AT FILLING ZONES AND OTHER OPERATING
    SPACES WHERE LEAKAGE IS PROBABLE. MECHANICAL FOR OTHER.
Protective Gloves:BUTYL RUBBER, PVA OR NEOPRENE
Eye Protection:CHEMICAL SPLASH GOGGLES
Other Protective Equipment:USE IMPERVIOUS CLOTHING IF THERE IS REPEATED
    OR PROLONGED CONTACT WITH LIQUID.
Work Hygienic Practices:PRE-EXISTING EYES AND SKIN DISORDER MAY BE
    AGGRAVATED TO EXPOSURE TO THIS PRODUCT.
Supplemental Safety and Health
RESEARCH TECHNOLOGY BOUGHT FREON 113 FROM ALLIED AND SUPPLIED TO
    THOMPSON-HAYWARD CHEMICAL COMPANY WHO IN RETURN SOLD TO DLA.

==================  Physical/Chemical Properties  ==================

HCC:N1
Boiling Pt:B.P. Text:116F,47C
Decomp Temp:Decomp Text:250F,121C
Vapor Density:6.5 (AIR=)
Spec Gravity:1.57@21.1C
Evaporation Rate &amp; Reference:2 (ETHER=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:COLORLESS LIQUID WITH ETHEREAL ODOR
Percent Volatiles by Volume:100

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, FINELY DIVIDED BARIUM,AND LITHIUM.POWDERED
    ALUMINUM,MAGNESIUM AND ZINC.
Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES AND OTHER SOURCES
    OF IGNITION
Hazardous Decomposition Products:DECOMPOSED BY HIGH TEMPERATURES TO
    FORM HALOGENS, HALOGEN ACIDS, AND CARBONYL HALIDES, INCLUDING
    PHOSGENE.

====================  Disposal Considerations  ====================

Waste Disposal Methods:COMPLY WITH FEDERAL, STATE AND LOCAL
    REGULATIONS. REMOVE TO A PERMITTED WASTE DISPOSAL FACILITY.

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