ASHLAND CHEMICAL CO. -- FREON TMS,650LB  -- 6850-00K000311
<pre>=====================  Product Identification  =====================

Product ID:FREON TMS,650LB
MSDS Date:01/01/1985
FSC:6850
NIIN:00K000311
MSDS Number: BBZTC
=== Responsible Party ===
Company Name:ASHLAND CHEMICAL CO.
Emergency Phone Num:606-324-1133
CAGE:5A188
=== Contractor Identification ===
Company Name:ASHLAND CHEMICAL CO
Address:5200 PAUL BLAZEL MEMORIAL PARKWAY
Box:City:DUBLIN
State:OH
ZIP:43017
Country:US
Phone:614-889-4505
CAGE:5A188

=============  Composition/Information on Ingredients  =============

Ingred Name:FREON TMS (90-95 %)
Fraction by Wt: >90%.
ACGIH TLV:1000 PPM

Ingred Name:METHYL ALCOHOL (METHANOL)  (SARA III)
CAS:67-56-1
RTECS #:PC1400000
Fraction by Wt: >5.0%
OSHA PEL:S,200PPM/250STEL
ACGIH TLV:S,200PPM/250STEL; 93
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS

=====================  Hazards Identification  =====================

Effects of Overexposure:EYES:MODERATE
    IRRITATION,REDNESS,TEARING;SKIN:SLIGHT IRRITAT;BREATHNG:RESPIRATORY
    IRRITAT.,NAUSEA

=======================  First Aid Measures  =======================

First Aid:SKIN: THOROUGHLY WASH EXPOSED AREA W/SOAP & WATER.;
    EYES:FLUSH W/LARGE AMTS. OF WATER. -GET MEDICAL ATTEN.;INHALATION:
    REMOVE PERSON TO FRESH AIR,IF BREATHING DIFFICULT, GIVE OXYGEN.
    DONOT GIVE STIMUL ANTS.

=====================  Fire Fighting Measures  =====================

Extinguishing Media:NON FLAMMABLE
Fire Fighting Procedures:USE SELF-CONTAINED BREATHING APPARATUS W/FULL
    FACE PIECE
Unusual Fire/Explosion Hazard:NONE

==================  Accidental Release Measures  ==================

Spill Release Procedures:SMALL SPILL:ALLOW TO EVAPORATE. VENTILATE
    AREA.; LARGE SPILL: STOP SPILL, AT SOURCE DIKE AREA OF SPILL TO
    PREVENT SPREADING, PUMP LIQUID TO SALVAGE TO SALVAGE TANK. USE
    SAND,CLAY,EARTH, FLOOR ABSORBEN T OR OTHER ABSORBENT MATERIAL FOR
    REMAINING LIQUID

======================	Handling and Storage  ======================

Handling and Storage Precautions:CONTAINER OF MATERIAL MAY BE HAZARDOUS
    WHEN EMPTIED.

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:NIOSH/MESA SELF-CONTAINED APPARATUS IF TLV >
    ESTABLISHED VALVE.
Ventilation:SUFFICIENT TO MAINTAIN EXPOSURE BELOW ESTABLISHED TLV.
Protective Gloves:POLYVINYL ALCOH
Eye Protection:CHEM.SPLASH GOGGLES.
Other Protective Equipment:NORMAL WORKING CLOTHING COVERING ARMS &
    LEGS.
Supplemental Safety and Health

==================  Physical/Chemical Properties  ==================

HCC:N1
Boiling Pt:B.P. Text:103 F
Vapor Pres:273
Vapor Density:2.8
Spec Gravity:1.52
Evaporation Rate &amp; Reference:UNAVAILABLE
Percent Volatiles by Volume:100

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
ALKALI METALS, POWDERED METALS

====================  Disposal Considerations  ====================

Waste Disposal Methods:SMALL:ALLOW VOLATILE PORTION TO EVAPORATE IN
    HOOD. ALLOW SUFFIC. TIME FOR VAPORS TO COMPLETELY CLEAR HOOD DUCT
    WORK. DESTROY REMAINING BY BURNING.; LARGE: USE LIQUID INCINERATION
    WITH OFF-GAS SCRUBBER . CONTAMIN. ABSORBENT,LANDFILL IAW
    REGULATIONS.

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